Jeffrey Elbert- Research Interests and
Opportunities
I
welcome undergraduate students to consider working in my group on chemistry and
related projects. The projects can last
any length of time and fulfill many different academic goals. Research for credit (independent study,
honors sections, etc), research for work study or summer stipend (Summer
Fellowship and research grant support, subject to availability) or other class
credit is possible. All research
projects in my group are serious projects for which I am actively seeking grant
support. There are no canned
projects. This means I ask serious
effort from the people working with me.
Students
that do well in my research group typically have completed Organic Chemistry I
and II and Organic Lab and have taken or are enrolled in Physical Chemistry
Kinetics/Quantum/Spectroscopy and Physical Chemistry Thermodynamics. Advanced Lab and Organic Structure Analysis
are also useful courses as well as Advanced Organic.
I am
looking for students that are curious and willing to spend time thinking about
the project. If you are looking for a
challenging project that will require you to push yourself beyond your
coursework, I have several projects that may be of interest to you.
Please
see me if you are interested in a research project.
All projects in my group require students to learn and
use a variety of instrumentation and techniques. You will routinely use NMR, GC/MS, IR and
HPLC. In addition, UV-Vis and
fluorescence spectrophotometry are also used.
Several projects will rely on laser spectroscopy (kinetic absorption and
flash photolysis). Vacuum line
techniques, chromatography, synthetic techniques and general photolysis
techniques are all important.
The projects I am currently focused on are;
Naphthalimde
Ligands
Naphthalimides substituted with polyamines have proven to be very interesting
transition metal and post-transition metal probes. The coordination of
the ligand with a metal ion is studied by absorbance, fluorescence, NMR, and
pH. We are currently measuring the effect of different metal ions and
different metal ion concentrations on the signals from each type of
spectroscopy, as well as measuring the complexation coefficients by pH
titration. We are trying to determine the metal ion property that best
correlates with the effect on the spectroscopic property measured and the
complexation strength.
Charge Transfer Compounds as Sensitizers
for Dye Sensitized Solar Cells
Compounds coupling electron donor groups with electron
acceptor groups through a conjugated system are targets in our efforts to make
new sensitizers for photovoltaic devices, specifically, Dye Sensitized Solar
Cells. Spatially separated frontier
orbitals are necessary for charge injection to a semiconductive (TiO2)
layer.
We are coupling fluoreneone
acceptor with ferrocene donor.
We are also coupling diaryl and triaryl amino donors
with various acceptors.